Water influence on the kinetics of transesterification using CaO catalyst to produce biodiesel
نویسندگان
چکیده
This research investigated the water influence on biodiesel production via transesterification, and especially their kinetic parameters. The initial rate of transesterification was increased with increasing amount (0–5 wt%). On contrary, significantly reduced for concentration 8–15 wt%. Moreover, when yield reached maximum value 30–40%, saponification as a side reaction became more significant presence emulsion phase, resulting in remarkable decrease yield. simple model including constant apparent activation energy revealed that containing 5 wt% gave higher compared to case absence water. However, could not describe high content. effect should be accounted adsorption term. modified Langmuir-Hinshelwood effects contamination originally proposed. Our finding suggested despite small content using CaO catalyst giving rise rate, feedstocks avoided because notable saponification.
منابع مشابه
Biodiesel transesterification kinetics monitored by pH measurement.
Quantification of a pH change that was observed over the course of the transesterification reaction that converts vegetable oil to biodiesel may provide a simple method to monitor the reaction. Transesterification of canola oil at 6:1 methanol to oil ratio with 0.5 wt.% KOH as catalyst was studied at 25, 35, and 45 °C. Reaction conversion was correlated to pH measurements and the results were s...
متن کاملTransesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
Biodiesel is an environmental friendly liquid fuel similar to conventional diesel in combustion properties. It has received international attention in recent times, as that biodiesel is renewable, non-toxic and safe to store. In this study, high grade biodiesel was produced from microalgae (Nannochloropsis oculata) derived lipids via transesterification reaction with methanol in the presence of...
متن کاملthe influence of the neo-platonic concept of poetic imagination on wordsworth’s poetry
بر اساس نظریه افلاطون در باره شعر خلاقیت هنری مورد انتقاد قرار گرفته است. نظریه کلی در مورد شعر این بود که شعر از ظواهرتقلید میکند و نه حقیقت. چون سایه ای از حقیقت است. اما با پیدایش فلسفه نو افلاطونی، انتقاتات قبلی در مورد شعر و شاعری اصلاح شد. فلوطین در کتاب انئید، اساس خلق هنری را بر محور مُثل افلاطونی قرار داد. وی باور داشت که هنر مندان در خلق آثار هنری، تحت تاثیر مُثل افلاطونی بوده و عوالمی ...
Synthesis and Characterization of CaO-TiO2 for Transesterification of Vegetable Palm Oil
This study explores the potential of titanium oxide impregnated on calcium oxide (CaO-TiO2) as catalyst in transesterification of vegetable palm oil (VPO) to produce biodiesel. The biodiesel yield increased with catalyst calcination temperature and reaction time, and the usage of CaO-TiO2 led to higher biodiesel production when compared to reaction catalyzed by CaO. Biodiesel yield of 93.33% wa...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Fuel
سال: 2021
ISSN: ['0016-2361', '1873-7153']
DOI: https://doi.org/10.1016/j.fuel.2021.120653